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Concern about potential military
toxics buried beneath the landfill pictured at left prompted
our investigation.
Sampling on Kodiak Island in
collaboration with Kodiak Community Conservation Network.
Please see the attached report (below) for a summary of our
results.
Report on Kodiak Sampling
Project
January 25, 1998
Background
Tim Vallianos, a Kodiak restaurant owner, contacted
Pamela Miller of Alaska
Community Action on Toxics in the spring of 1997 to express
concerns about
his family's health. His daughter and son, ages 2 and 5
respectively, had
been tested for toxic metals in their hair. Analytical work
done by a clinic
revealed elevated levels for certain metals such as
mercury. The children
had also been exhibiting behavioral and neurological
symptoms (his daughter
experienced convulsions) that Tim believed were associated
with the
exposures. As a result of his concerns, the family moved
from the island,
selling their home and business, during the summer of 1997.
During this
time, Pamela Miller communicated with Tim by phone and
recommended medical
facilities that treat occupational and environmental
exposures to contaminants.
Before Tim left Kodiak, he talked with neighbors and old
timers about
potential sources of contamination that may be causing his
family's health
problems. He came to the conclusion that contamination from
past military
activities, specifically dumping of munitions and other
materials, may be
the source of the problem. His home (at 2010 Mill Bay Road)
was situated on
a substantial fill which may be been used to cover a source
of
contamination, such as a dump site or landfill. The fill
had been situated
upon a series of wetlands and a stream system and thus were
very wet Tim had
to have a sump pump constantly pumping water from the lower
level of his home.
He also related that his family's problems were not
isolated that other
families in the area are experiencing similar problems. A
woman who is a
taxi driver with a home nearby has had medical
difficulties, including loss
of weight and neurological problems. People in the trailer
court nearby are
sick, with children experiencing learning and behavioral
disorders. His
Mexican neighbors are also sick (woman, age 41; husband,
and 4 children).
Pamela Miller began searching for background information
through the Freedom
of Information Act. Although these documents
revealed significant
contamination problems associated with military activities
in several
locations around Kodiak, we could not find documentation of
dumping in the
immediate area of Tim's home. The primary contaminated
military facilities
on Kodiak that are in various stages of cleanup include:
1) Kodiak Armory, Alaska Army National Guard (status,
closed);
2) Pillar Mountain RRS, Air Force
3) Burma Road, U.S. Army Corps of Engineers
4) Buskin Beach, U.S. Army Corps of Engineers
5) Kodiak Army site, U.S. Army Corps of Engineers
6) Kodiak Coast Guard Support Center (formerly a U.S. Navy
site until
1972), U.S. Coast Guard and Army Corps of Engineers
7) Fort Tidball on Long Island, Department of the Army
8) Bruhn Point Landfill, Department of the Army
There appears to be little or no public oversight of the
cleanup of these
facilities to ensure responsible cleanup that is protective
of environmental
and human health. Further investigation is necessary to
fully reveal the
nature and extent of contamination from military facilities
on Kodiak. There
are significant gaps in the sampling data that are
accessible from EPA and
the military.
In addition, the Federal Aviation Administration has
created contamination
problems at their airport, Pillar Mountain, and Woody
Island facilities.
The most serious and apparent problems that have been
documented through
sampling by the USGS and others include contamination from
Navy and Coast
Guard facilities on the Nyman Peninsula/Womens Bay and
within the Buskin
River watershed.
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Summary of Information from US
Geological Survey Reports
1) Hydrologic and Water Quality Data for U.S. Coast Guard
Support Center,
Kodiak, Alaska, 1987-89 (USGS Open-File Report 96-498,
1996). The US Coast
Guard Center was established and remained as a Navy base
until 1972, serving
as a submarine base, air base, and port. USGG soil sampling
(100 samples) in
the area (and two lake-bed samples) revealed: total
petroleum hydrocarbons
were detected at 16 site. O and p-xylenes and
tetrachloroethene were
detected at 3 sites; toluene was detected at 2 sites; and
vinyl chloride,
methylene chloride, trichloroethene, and m-xylene were each
detected once.
Lead was found at all but one site, ranging from 0.3 to 100
mg/kg (ppm).
USGS collected about 350 groundwater samples from 101
wells; 110 surface
water samples were collected from 59 sites on streams and
lakes. Cadmium,
lead, thallium, benzene, tetrachloroethene, trichloroethene,
and vinyl
chloride were detected at concentrations greater than
allowed by EPA's
primary drinking water regulations. Arsenic, cadmium, lead,
sulfate,
thallium, benzene, chloroform, 1,2-dichloroethane,
methylene chloride,
tetrachloroethene, 1,1,1-trichloroethane, vinyl chloride,
PCBs and styrene
were detected at concentrations higher than Maximum
Contaminant Level Goals
established by EPA. This report identified 18 areas of
contamination in the
Buskin River watershed and Nyman Peninsula.
2) Overview of Environmental and Hydrogeologic Conditions
near Kodiak,
Alaska (USGS Open-File Report 95-406, 1995). USGS water
samples
from wells near the airport FAA facilities included
exceedances of EPA's
Maximum Contaminant Levels (MCL) for lead a well A79 water
sample had lead
concentration of 0.019 mg/L (MCL is 0.005 mg/L); a well B1
water sample had
a toluene concentration of 6.5 mg/L (MCL is 1 mg/L).
Concentrations greater
than reporting levels were also found in groundwater
samples for
chloromethane, trichlorofluoromethane, aluminum, lead,
mercury, arsenic and
zinc.
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October 1997 Sampling on Kodiak
Island
Pamela Miller, Alaska Community Action on Toxics, and
Kristin Stahl-Johnson,
Kodiak Community Conservation Network, collected a total of
11 samples,
including soil, sediment, and water samples on October 21,
1997. The samples
were shipped to the Citizens Environmental Laboratory using
chain of custody
procedures. The Citizens Environmental Laboratory performed
the analytical
work and prepared a report (dated November 18, 1997). The
sampling focused
on the drainage entering and passing underneath the massive
fill parallel to
Mill Bay Road in the vicinity of Tim Valliano's former
home. We also took
samples downgradient from Smoky's dump and just upstream
from the entrance
to Island Lake.
Sample descriptions
Soil/Sediment samples
1) sediment sample from stream near trailer park
below outfall from lake
(grab sample);
2) soil sample from base of home foundation at 2010 Mill
Bay Road (grab
sample);
3) soil sample taken from center of backyard at 2010 Mill
Bay Road (grab
sample);
4) soil sample taken from outflow of sump pump in backyard
of 2010 Mill Bay
Road (grab sample);
5) sediment sample taken from flooded basement outside
dilapidated,
abandoned house 2 doors down from 2010 Mill Bay Road (grab
sample);
6) sediment sample taken from downstream side of fill below
culvert (grab
sample);
7) soil sample from Smoky's dump at seep in downgradient
berm (grab sample);
8) sediment sample from toe of fill, Smoky's dump
(composite sample);
9) sediment sample from stream just upstream from entrance
into Island Lake
(grab sample).
Water samples
1) 1 liter water sample taken below outfall (same
location as #6 above);
2) 1 liter water sample taken downgradient from fill below
the outfall at
Smoky's dump.
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Heavy Metal Results (see Citizens Environmental
Laboratory Report)
Aluminum
Aluminum concentrations ranged from 10,100 mg/kg
(Sample 6) to 32,700 mg/kg
(Sample 7) in the soil/sediment samples. In water sample 1,
the aluminum
concentration was 2.52 mg/L. Water sample 2 had no
detectable aluminum. (EPA
Method 6010/200.7)
Mean and median background concentrations for aluminum in
uncontaminated
stream and lake sediments in Alaska are 5.8 and 6.2 ppm (=
mg/L)
respectively. The highest concentration measured in Alaska
in
uncontaminated stream and lake sediments was 82 ppm. Our
samples, that
ranged from 10,100-32,700 mg/kg (= mg/L), are higher by
three orders of
magnitude. Water sample #1 concentration of 2.52 mg/L
exceeds secondary
maximum contaminant levels for drinking water (0.05 mg/L)
by two orders of
magnitude.
Antimony
Antimony concentrations ranged from non-detectable
(Samples 1, 2, 4, 7, 8)
to 1.02 mg/kg in Sample 6. Antimony was not detected in the
two water
samples. (EPA Method 7041/204.2
Arsenic
Arsenic concentrations ranged from 8.32 mg/kg (Sample
4) to 41.9 mg/kg
(Sample 1) in soil/sediment samples. Sample 6 also had a
relatively high
concentration of arsenic at 38.4 mg/kg. Arsenic
concentrations in the two
water samples was 0.0113 and 0.0052 mg/L, respectively.
(EPA Method 7060/206.2)
Arsenic values exceed mean and median background levels for
uncontaminated
stream and lake sediments (17.3 and 12.0 mg/kg,
respectively), as well as
the arithmetic and geometric means for soils (9.6 and 6.7
mg/kg,
respectively). The arsenic concentration in water sample #1
approaches
that of the MCL for drinking water (0.05 mg/L).
Cadmium
Cadmium concentrations ranged between 2.1 mg/kg (Sample
2) and 28.9 mg/kg
(Sample 6) in soil/sediment samples. Cadmium was not
detected in the two
water samples (detection limit is 0.010 mg/kg). (EPA Method
6010/200.7)
Cadmium concentrations measured in background soil samples
from Kodiak
Island are 2, 4, and 13 ppm (= mg/kg) . The highest value
that we detected
was 28.9 mg/kg in the sediment sample at the outfall below
the massive fill
along Mill Bay Road. Cadmium may be elevated from
contamination from
munitions or other military/industrial waste disposal. This
requires further
investigation.
Lead
Lead concentrations ranged from non-detectable (Sample
3) to 46 mg/kg
(Sample 1) in sediment/soil samples. Lead was not detected
in the two water
samples (detection limit is 0.0050 mg/kg). (EPA Method
6010/239.2/7421)
Lead concentrations exceed the arithmetic and geometric
mean values for
background lead concentrations in soils throughout Alaska
(14 and 12 mg/kg,
respectively). Lead concentrations in our samples exceeded
even the mean
and median lead concentration of over 100 soil samples and
two lake-bed
samples taken by USGS in investigating the contamination
from the Navy and
Coast Guard facilities on Kodiak (those values are 10.6
mg/kg and 9.8
mg/kg). Lead concentrations commonly range between 15-25
mg/kg in soils.
Lead may be elevated as a result of contamination such as
munitions,
batteries, or other metal debris.
Mercury
Mercury concentrations ranged from 0.10 mg/kg (Samples
3 and 4) to 0.41
mg/kg (Sample 5). Mercury was not detected in the two water
samples
(detection limit is 0.00050 mg/kg). (EPA Method
7471/245.1/7470)
Nickel
Nickel concentrations ranged from 15.1 mg/kg (Sample 3)
to 67.8 mg/kg
(Sample 1). Nickel was not detected in the two water
samples (detection
limit is 0.030 mg/kg). (EPA Method 6010/200.7)
Pesticides and PCB Analyses (see Citizens
Environmental Laboratory Report)
No pesticides or PCBs were detected in the samples. The
laboratory used EPA
Method 8080A for the analysis. Only Samples 4, 7, and 8
were analyzed for
pesticides and PCBs.
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Total Petroleum Hydrocarbons (TPH)
(see Citizens Environmental Laboratory Report)
Two samples had positive results for the detection of TPH,
Sample 7 (1,100
mg/kg) and 8 (680 mg/kg). TPH was not detected in Sample 4.
Only Samples 4,
7 and were analyzed for TPH.
TPH concentrations in these two samples greatly exceed
Alaska Department of
Environmental Conservation soil cleanup guidelines for the
remediation of
gasoline (10 mg/kg) and non-gasoline (100 mg/kg) releases.
Since petroleum
product has been found in sediments downgradient from the
dump, there is
potential for the petroleum to move
downstream. This may pose a threat to environmental and
human health.
Children play in the area, wildlife and pets drink from the
stream flowing
from the dump.
Conclusions
The heavy metals cadmium and lead appear to be elevated
above normal
background levels, although little comparative data exist
for Kodiak.
Aluminum levels far exceed normal background values.
Arsenic also exceeds
normal background levels for Alaska for sediments.
Levels of petroleum hydrocarbons leaching out of Smoky's
dump are elevated
above action levels.
Fortunately, no pesticides or PCBs were detected. Given the
level of
pesticides and PCBs used and detected in other areas of
Kodiak from military
activities, a comprehensive assessment of pesticide and PCB
levels, that
includes freshwater and marine food web sampling around the
island, should
be made.
Recommendations and
Actions Needed
1) Greater public oversight of cleanup of
military and other federal
facilities on Kodiak, through FOIA, document review,
participation in CERCLA
process, independent scientific review of the military
contractor's sampling
design and implementation;
2) Integration and interpretation of sampling results from
military, USGS,
Borough, and other programs;
3) Interviews with Kodiak elders and former military
personnel to better
understand locations and nature of military dump sites;
4) FOIA and archival review of information on offshore
dumpsite(s);
5) Additional community-based environmental sampling and
health surveys;
6) Action should be taken to characterize and contain
potentially hazardous
wastes in Smoky's dump. A comprehensive sampling program
should be initiated
immediately to fully characterize petroleum and other
hazardous chemical
leaks that may pose a threat to environmental and human
health;
7) Action should be taken to determine the nature of
potentially hazardous
materials buried beneath the massive fill along Mill Bay
Road in the
vicinity of the trailer park and Tim Valliano's former
home.
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